Demonstration of an Automated System for Vertical Profiles of Volatile Organic Compounds

Volatile organic compounds (VOCs) play important roles throughout the atmosphere, many of which are altitude dependent. This highlights the need for easily deployable devices to sample VOCs across different atmospheric layers. To address this, we present the design and initial application of a Time Resolved Automated Volatile organIc compounds Sampling system (TRAVIS). VOCs are collected on sorbent tubes, which are subsequently analyzed by a thermal desorption gas chromatography mass spectrometry pipeline. TRAVIS leverages a piezoelectric pump with an integrated pressure sensor for precise (0.1% flow rate relative standard deviation) and accurate (−3 ± 2% error in VOC quantitation) measurements. Via deployment on a tethered balloon system over an agricultural area, TRAVIS is used to show consistent vertically resolved VOC concentrations in a well-mixed (i.e., turbulent) atmosphere (e.g., 5% relative standard deviation for isoprene) and vertically dependent concentrations for a stratified atmosphere (e.g., prior to boundary layer development). Furthermore, we also show VOC information from an intermittent plume via both targeted and untargeted analysis, highlighting future applications for spurious events in agriculture, air quality monitoring, and environmental impact. Overall, the development of TRAVIS represents a lightweight, accurate, sensitive, and precise VOC sampling module for the scientific community.. Authors: Vandergrift, Gregory W. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)] (ORCID:0000000289629897); Liu, Sijia [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Univ. of California, Irvine, CA (United States)] (ORCID:0000000269582868); Liyu, Andrey V. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)] (ORCID:0000000296576770); Cheng, Zezhen [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)] (ORCID:0000000163204519); Lindquist, John M. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]. DOE Contract: AC05-76RL01830; FG03-00ER62913; FG03-97ER62338. Subjects: Aerosols; Computer simulations; Hydrocarbons; Volatile organic compounds; atmospheric chemistry; automation; modular; unmanned sampler; volatiles