Group hexavalent actinide separation from lanthanides using sodium bismuthate chromatography

Advanced used nuclear fuel (UNF) reprocessing strategies are limited by the complex radiochemical separations and engineering required to achieve the separation of actinides (An) from neutron scavenging lanthanides (Ln). The accessibility of the hexavalent oxidation state for the actinides (U – Am) provides a pathway to achieving a group hexavalent actinide separation from the trivalent lanthanides and Cm. The solid oxidant and ion exchanger, sodium bismuthate (NaBiO₃), has been demonstrated to quantitatively oxidize and separate Am from trivalent Cm in a column chromatographic system. This work expands on the use of NaBiO₃ chromatography to characterize the adsorption, kinetic, and elution behavior of U, Pu, and Eu. Separation factors over 200 with rapid kinetics were observed at dilute nitric acid concentrations with a complete An/Ln separation achieved in under an hour. In conclusion, the adsorption and chromatographic behavior of key fission products present in various reprocessing raffinates was characterized which demonstrated potential application of a NaBiO₃-based separation following a TRUEX process.. Authors: Labb, Samantha A. [Colorado State University, Fort Collins, CO (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000152412726); Kmak, Kelly N. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)]; Despotopulos, John D. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)]; Kerlin, William M. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000306379624); Sudowe, Ralf [Colorado State University, Fort Collins, CO (United States)] (ORCID:0000000201632128). DOE Contract: AC52-07NA27344. Subjects: 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; Actinides; Chromatography; Fission products; Lanthanides; Sodium bismuthate