Predictive Assessment of the Chemical Composition of Coal Ash in Reserve at U.S. Disposal Sites

In the United States, more than 2 Gt of coal combustion residuals (i.e., coal ash) are stored in hundreds of disposal units. Recent federal regulations mandate the closure or retrofitting of most coal ash impoundments, presenting significant challenges for waste management. These regulatory pressures also present opportunities to reuse coal ash. However, the quality and quantity of discarded coal ash across the U.S. are not well known, even though this information is crucial for spurring its reuse for conventional and new material applications. This study describes a predictive model for the major element composition of coal ash in reserve at disposal sites of major U.S. coal-fired power plants. This model was constructed from coal purchase records of 705 power stations from 1973 to 2022 and was trained on coal ash composition data, showing that coal ash elemental composition is strongly associated with the source of feedstock coal. The model showed regional shifts in the major element contents of ash produced by power plants in the last 50 years, particularly for calcium and iron (expressed as %CaO and %Fe2O3), as power stations changed their source of coal over this time frame. Our approach enables an estimation of chemical composition for ash stored in waste impoundments at individual power stations. Such information can help to delineate the regional market resource potential of supplementary cements for concrete and other material innovations that would utilize coal ash harvested from disposal sites across the U.S.. Authors: Jin, Zehao [Department of Civil & Environmental Engineering; Duke University] (ORCID:0000000324987164); Huang, Junkai [Duke University, Durham, NC (United States)]; Hower, James C. [University of Kentucky, Lexington, KY (United States)] (ORCID:0000000346942776); Hsu-Kim, Heileen [Duke University, Durham, NC (United States)] (ORCID:0000000306754308). DOE Contract: FE0031748. Subjects: 01 COAL, LIGNITE, AND PEAT; coal; coal combustion residues; decarbonized infrastructure materials; elements; energy data; power; reaction products; redox reactions; waste recycling