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Technoeconomic and life cycle energy analysis of carbon fiber manufactured from coal via a novel solvent extraction process

DOE

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Coal is a versatile energy resource and was a driver of the industrial revolution that transformed the economies of Europe and North America and the trajectory of civilization. In this work, a technoeconomic analysis was performed for a coal-to-carbon-fiber manufacture process developed at the University of Kentucky’s Center for Applied Energy Research. According to this process, coal, with decant oil as the solvent, was converted to mesophase pitch via solvent extraction, and the mesophase pitch was subsequently converted to carbon fiber. The total cost to produce carbon fibers from coal and decant oil via the solvent extraction process was estimated to be $\$$11.50/kg for 50,000-tow pitch carbon fiber with a production volume of 3750 MT/year. The estimated carbon fiber cost was significantly lower than the current commercially available PAN-based carbon fiber price ($\$$20–$\$$30/kg). With decant oil recycling rates of 50% and 70% in the solvent extraction process, the manufacturing cost of carbon fiber was estimated to be $\$$9.90/kg and $\$$9.50/kg of carbon fiber, respectively. A cradle-to-gate energy assessment revealed that carbon fiber derived from coal exhibited an embodied energy of 510 MJ/kg, significantly lower than that of conventionally produced carbon fiber from PAN. This notable difference is primarily attributed to the substantially higher conversion rate of coal-based mesophase pitch fibers into carbon fiber, surpassing PAN fibers by 1.6 times. These findings indicate that using coal for carbon fiber production through solvent extraction methods could offer a more energy-efficient and cost-competitive alternative to the traditional PAN based approach.. Authors: Nagapurkar, Prashant [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)] (ORCID:0000000285406717); Lara-Curzio, Edgar [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)]. DOE Contract: AC05-00OR22725. Subjects: 01 COAL, LIGNITE, AND PEAT; Carbon fiber; Coal to carbon fiber; Life cycle Energy; Solvent extraction; Techno-economic analysis

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