Understanding the impacts of inorganic species in woody biomass for preprocessing and pyrolysis–A review

Woody biomass represents an abundant resource for sustainable biofuels, biochemicals, and bioproducts. Technologies for converting woody biomass have been established for decades, and research consistently highlights the critical role of inorganic species and ash plays in feedstock handling and conversion processes, including equipment plugging, corrosion, and catalyst deactivation. A thorough understanding of the variability, transport behavior, and downstream impact of inorganic species in woody biomass is essential for defining feedstock quality specifications and developing effective management strategies for conversion processes. This review compiles critical information in five main sections: 1) inorganic species concentration in woody biomass, based on anatomical fractions and their sources of variability; 2) technique features for quantifying inorganic elemental chemical analysis; 3) impacts of inorganic species on biomass preprocessing; 4) impacts of inorganic species on pyrolysis, and 5) mitigation strategies. Additionally, this review explores future challenges and opportunities in addressing the impacts of inorganic species on biomass quality. These insights aim to support the sustainable development of the biomass-to-bioenergy pipeline and ensure high-quality lignocellulosic feedstocks for efficient downstream conversions. The findings offer valuable guidance to policy makers, industry stakeholders, and researchers in developing effective strategies for managing inorganic species in woody biomass and fostering the sustainable processes for lignocellulosic biorefineries.. Authors: Ding, Ling [Idaho National Laboratory (INL), Idaho Falls, ID (United States)] (ORCID:0000000260355976); Cheng, Ming-Hsun [Univ. of Idaho, Idaho Falls, ID (United States); Center for Advanced Energy Studies, Idaho Falls, ID (United States)] (ORCID:0000000234287535); Lin, Yingqian [Idaho National Laboratory (INL), Idaho Falls, ID (United States)]; Lin, Kuan-Ting [Idaho National Laboratory (INL), Idaho Falls, ID (United States)]; Sale, Kenneth L. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)] (ORCID:0000000242698940). DOE Contract: AC02-05CH11231; AC07-05ID14517; AC36-08GO28308; NA0003525. Subjects: 09 BIOMASS FUELS; characterization; feedstock quality attributes; feedstock variability; inorganic species; pyrolysis; transport behavior; woody biomass