Blending as an In-Tank Waste Processing Strategy: Year 1 Progress Report

The Hanford Site stores approximately 56 million gallons of radioactive legacy defense waste in underground tanks. Direct feed of southeast quadrant tank waste to a high-level waste treatment facility is currently being explored to accelerate tank treatment activities. This study seeks to de-risk waste transfers by favorably altering the resuspension and critical velocities of wastes through strategic waste blending. Wastes rich in aluminum- and zirconium-bearing solids pose significant risks due to their high settled strength and density. A series of tests explores how solid phase particle size and suspending phase chemistry alter waste transport properties, quantified through the just-suspended mixing speed (NJS), for pure and blended aluminum- and zirconium-bearing waste solid simulants. The study utilizes a range of gibbsites (three sizes spanning 10 to 90 µm) and zirconia solids (three sizes spanning 10 to 100 µm). As expected, the NJS of pure solids largely follows predictions based on literature correlations; blends of gibbsite and zirconium-bearing solids of differing particle sizes exhibit NJS maxima attributed to dense packing of the mixed-size settled solids. The findings of this study will assist in developing strategies to optimize the transport of waste solids for the safe and efficient delivery of tank waste.. Authors: Daniel, Richard C. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)] (ORCID:0000000204317094); Burns, Carolyn A. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)] (ORCID:0000000274371889); Chowdhury, Shakibur Rahaman [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]; Huynh, Phong L. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]; Peterson, Reid A. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)] (ORCID:0000000333681896). DOE Contract: AC05-76RL01830. Subjects: 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES