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Surface water and groundwater FTICR-MS, NPOC, and TN from nine wetlands and three upland wells at the Tanglewood Biological Station, Alabama

DOE

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This dataset supports a broader study examining wetland hydrobiogeochemical responses to flood disturbance and the subsequent impacts on watershed nutrient export. The study was designed following ICON (integrated, coordinated, open, and networked) principles. Samples were collected from nine wetlands and three upland wells at the Tanglewood Biological Station, Alabama in August 2024 and February 2025, during the dry and wet season, respectively. The contents include geochemistry (dissolved organic carbon measured as non-purgeable organic carbon; total dissolved nitrogen) and organic matter characterization (FTICR-MS). Related water level data from the same locations can be found at https://data.ess-dive.lbl.gov/view/doi:10.15485/2530253. Additional geochemistry will be published in a separate data package. For details on how to navigate this data package, see this infographic from the River Corridor SFA https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions.This dataset is comprised of (1) a folder containing environmental context photos; (2) file-level metadata; (3) data dictionary; (4) field metadata; (5) readme; (6) international generic sample number (IGSN) mapping file; (7) the field protocol; and (8) a subfolder with sample data. The sample data subfolder contains (1) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data and averages; (2) total nitrogen data and averages; (3) methods codes; and (4) a subfolder of 12 Tesla (12T) Fourier-transform ion cyclotron resonance mass spectrometry (FTICR-MS) data. All files are .csv, .pdf, .jpeg, or .jpg.. Authors: Forbes, Brieanne [Pacific Northwest National Laboratory] (ORCID:0000000192409687); Danczak, Robert E. [Pacific Northwest National Laboratory] (ORCID:000000031396192X); Delgado, Dillman [Pacific Northwest National Laboratory] (ORCID:0000000166526775); Garayburu-Caruso, Vanessa A. [Pacific Northwest National Laboratory] (ORCID:0000000333836237); Goldman, Amy E. [Pacific Northwest National Laboratory] (ORCID:0000000304906451). DOE Contract: AC02-05CH11231. Subjects: 54 ENVIRONMENTAL SCIENCES; Biogeochemistry; Coordinated; DOC; Dissolved organic carbon; Disturbance; ESS-DIVE CSV File Formatting Guidelines Reporting Format; ESS-DIVE File Level Metadata Reporting Format; ESS-DIVE Location Metadata Reporting Format; ESS-DIVE Sample ID and Metadata Reporting Format; ESS-DIVE Water-Soil-Sediment Chemistry Reporting Format; FTICR-MS; Flood; Hydraulic exchange; Hydrobiogeochemical function; Hydrology; Hyporheic zone; ICON; Integrated; NPOC; Networked; Non-purgeable

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